Flame resistant fabrics with improved aesthetics and comfort, and method of making same

ABSTRACT

Fabrics having improved aesthetic characteristics in addition to good FR characteristics and strength are described, as well as a method for making the fabrics. The fabrics are made by subjecting a fabric containing inherently flame resistant fibers to a fluid treatment process such that a fabric with good comfort and aesthetic characteristics is formed. In one form of the invention, the fabric comprises plied yarns, and the fluid treatment process serves to separate the plies from each other. The fabrics have a soft hand, good protective characteristics, good strength and durability, as well as good wicking and soil release characteristics.

BACKGROUND OF THE INVENTION

A variety of occupations require workers to come into close contact with hot equipment, hot substances open flames, and electric arcs and the like. For example, oil refinery, petro chemical workers, electricians, military personnel, etc. typically operate in such environments. In order to minimize their risk of injury from the hot elements, such workers typically wear flame resistant apparel.

Flame resistant garments are generally made from flame resistant materials such as those made from aramid fibers (including meta-aramids and para-aramids), melamine fibers, or those treated with flame resistant “FR” chemistries. Prior protective garments have focused strictly on flame resistant protection and durability, since the garments must provide good protection to the wearer, and must withstand hazardous environments. In addition, because many garments are often laundered under industrial wash conditions, they must be capable of withstanding a number of such industrial launderings in order to have an acceptable useful life. For example, it is generally considered by the purchasers of these garments that the garments must last through a minimum of 125 industrial launderings. Therefore, the prior garments, which have tended to perform relatively well from the standpoint of protection and durability, have been extremely deficient in aesthetic characteristics such as wearer comfort. For example, they are known to be stiff and to have a harsh handle, and they are generally considered to be hot and uncomfortable to the wearers. Not only is the discomfort typically associated with these garments a source of displeasure to the wearers, but it may discourage them from wearing the equipment that would optimize their protection, thereby jeopardizing their safety. Furthermore, these garments are typically so uncomfortable as to require an undergarment of some sort to protect the wearer's skin, which can be undesirable when the garment is to be worn in hot environments.

There are two general types of FR apparel fabrics currently in the market. The first category is that of inherently flame resistant fibers (such as aramids, melamines, etc.) and the second category achieves flame resistance primarily through the subsequent application of chemistry to the fiber. Fabrics of inherently FR fibers are generally considered to provide greater durability, while chemically-treated fabrics (such as FR cotton) are often considered to provide a lesser degree of durability but at a lesser degree of discomfort to the wearer.

Past attempts to improve the comfort of FR garments have generally been directed to the garment construction, e.g. through the provision of garment vents and the like. As will be appreciated by those of ordinary skill in the art, the garment construction modifications made to enhance comfort can have a negative effect on wearer protection.

Therefore, a need exists for fabrics and garments that provide a good degree of FR protection to users, while providing a greater degree of user comfort and improved aesthetic characteristics. In addition, a need exists for a method of enhancing the aesthetic characteristics of FR fabrics and garments.

SUMMARY

With the foregoing in mind, it is therefore an object of the invention to provide flame resistant fabrics having improved wearer comfort at comparable levels of FR protection and strength to conventional FR fabrics.

It is also an object of the invention to provide FR fabrics having improved aesthetics relative to commercially-available FR fabrics, and in particular, relative to commercially-available fabrics made from inherently FR fibers.

It is also an object of the invention to provide a method for enhancing the comfort of FR fabrics, and for manufacturing FR fabrics having good comfort and aesthetic characteristics in combination with good strength and durability.

It is a further object of the invention to provide an FR fabric having improved strength and moisture absorption with improved cleanability and a reduced tendency for soil redeposition.

The general predictors of how comfortable a fabric will be to wear are the mechanical and surface properties of the fabric, the freedom of movement it affords a wearer (e.g. by draping well rather than being stiff), how well it manages moisture, and its air permeability. In addition, how comfortable a wearer will perceive a garment to be will also depend largely upon which part of the wearer's body the garment is worn and the environment (e.g. hot or cold, humid or dry, etc.) in which it is worn.

The present invention is directed to flame resistant fabrics that provide good protection to the wearer from short exposure open flame, and/or electric arc, while also providing enhanced aesthetics. In particular, the fabrics of the invention have superior hand, physical strength, durability, moisture transport, and soil release, and are more comfortable to the wearer than existing fabrics having comparable levels of FR protection.

In a preferred form of the invention, the fabric is a woven fabric having a weight of about 2 to about 12 oz/sq yard, and more preferably about 4 to about 8 oz/sq yard. In particular, fabrics in these weight ranges are particularly good in apparel type applications. The fabric can be of any desired weave construction, including but not limited to plain weave, twill weave (e.g. 2×1, 2×2, 3×1, etc.), basket weave, ripstop, and oxford weave.

The fabrics of the invention desirably comprise inherently flame resistant fibers (“FR fibers”). In a preferred form of the invention, the fabric is made predominately from (e.g. at least about 65%), or substantially entirely from, FR fibers.

It has been found that fabric blends including about 90% to 95% FR fibers perform well. Where the fabric is made substantially entirely from FR fibers, it may also include minor amounts of additional fibers to enhance certain characteristics of the fabric (e.g. physical, aesthetic, and/or performance characteristics such as, but not limited to strength, static dissipation, abrasion resistance, etc. without adversely impacting FR resistance to a substantial extent. Preferably, at least some of the FR fibers are provided in staple form and even more preferably substantially all of the FR fibers are provided in staple fiber form. To this end, it has been found to be desirable to manufacture the fabric at least partially and preferably substantially entirely, from spun yarns. In particular, where the fabric is a woven fabric, it has been found to be desirable to include spun yarns in at least the fabric warp.

The FR fibers can be of any commercially available variety within the scope of the invention, but are desirably selected from the group consisting of aramid fibers, meta-aramids, para-aramids, fluoropolymers and copolymers thereof, chloropolymers, polybenzimidazole, polyimides, polyamideimides, partially oxidized polyacrylonitriles, novoloids, poly(p-phenylene benzobisoazoles), poly)p-phenylene benzothiazoles), polyphenylene sulfides, flame retardant viscose rayons, polyvinyl chloride homopolymers and copolymers thereof, polyetheretherketones, polyketones, polyetherimides, polylactides, melamine fibers, or combinations thereof with other FR fibers or fibers that are not inherently flame resistant. In many instances, commercially-available spun yarns made from inherently FR fibers include minor quantities of other types of fibers such as Kevlar® brand fiber available from DuPont of Wilmington, Del., nylon, P-140 nylon with carbon core from DuPont, or the like, to enhance a fabric's strength, durability, ability to be processed in conventional textile equipment, etc. For example, a preferred fabric of the invention is made from Nomex® IIIA yarns, which contain approximately 95% aramid fiber, and 5% other fibers (Kevlar®) aramid and P-140 nylon/carbon), and are available from I.E. DuPont de Nemours of Wilmington, Del. Examples of some other commercially available FR fibers are those sold under the tradenames Kermel and Basofil, available from Rhodia of Colmar, France, and McKinnon-Land of Charlotte, N.C., respectfully.

The fabric of the invention is made by processing the fabric comprising inherently FR fibers with a fluid process designed to raise loops of fibers outwardly from the fabric surface, and form a plurality of fiber tangles that are primarily composed of fibers that are substantially intact and undamaged. Where the fabric comprises plied yarns, the fluid treatment process also desirably separates at least a portion of the plies from each other, detwists them, and causes fibers from adjacent plies to become entangled with each other.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a photomicrograph (30× magnification) of the unenhanced fabric of Example A;

FIG. 2 is a photomicrograph (30× magnification) of the enhanced fabric of Example B;

FIG. 3 is a photomicrograph (100× magnification) of the unenhanced fabric according to Example A;

FIG. 4 is a photomicrograh (100× magnification) of the enhanced fabric of Example B below;

FIG. 5 is a photomicrograph (200× magnification) of the unenhanced fabric of Example A; and

FIG. 6 is a photomicrograph (200× magnification) of the enhanced fabric of Example B below.

DETAILED DESCRIPTION

In the following detailed description of the invention, specific preferred embodiments of the invention are described to enable a full and complete understanding of the invention. It will be recognized that it is not intended to limit the invention to the particular preferred embodiment described, and although specific terms are employed in describing the invention, such terms are used in a descriptive sense for the purpose of illustration and not for the purpose of limitation.

The fabric of the invention desirably comprises inherently flame resistant fibers (“FR fibers”). In a preferred form of the invention, the fabric includes at least about 65% FR fibers, more preferably at least about 90% FR fibers, and even more preferably, at least about 95% FR fibers. Preferably, at least some of the FR fibers are provided in staple form and even more preferably, substantially all of the FR fibers are provided in the form of spun yarns. As will be appreciated by those of ordinary skill in the art, spun yarns can be made by a variety of production methods, including but not limited to open end spinning, air jet spinning, vortex spinning, ring spinning and the like.

In a preferred form of the invention, the fabric is made substantially entirely from spun yarns. Also in a preferred form of the invention, the yarns are formed of plural plies. Preferably, each of the plies comprises FR staple fibers. Where the fabric of the invention is in the form of a woven fabric, it is particularly preferred that plied spun yarns are provided in at least the fabric warp.

In a preferred form of the invention, the fabric is a woven fabric having a weight of about 2 to about 12 oz/sq yard, and more preferably about 4 to about 8 oz/sq yard. Where the fabric is to be used in the manufacture of industrial clothing such as pants, shirts and overalls, it has been found that fabrics having a weight of about 5.5-6.5 oz/ sq yd, and more preferably about 5.8-6.2 oz/sq yard perform well. For example, a fabric having an approximate weight of about 6 oz/sq yd would perform well as an industrial bottom weight fabric.

The fabric is preferably a woven fabric, and can be of any desired weave construction, including but not limited to plain weave, twill weave (e.g. 2×1, 2×2, 3×1, etc.), basket weave, oxford weave, satin weave, and jacquard weave. The fabrics can be woven according to conventional weaving processes.

The fabric desirably has first and second surfaces, with at least one surface having a plurality of fiber tangles that are composed primarily of fibers that are substantially intact and undamaged. When the fabric is formed from plied yarns, the individual plies are desirably at least partially separated from each other and individual fibers from different plies are entangled with each other.

As illustrated in the drawings, FIGS. 1, 3 and 5 are photomicrographs at 30×, 100×, and 200× magnification, while FIGS. 2, 4 and 6 are photomicrographs at the same levels of magnification (i.e 30×, 100× and 200×, respectively) of the fabrics of the invention. As can clearly be seen from the photomicrographs, the fabrics of the invention are characterized by a plurality of fiber tangles or teased loops that are comprised of fibers that are substantially intact and undamaged, as opposed to the unenhanced fabrics which have very little entanglement of the fibers and little surface effect. Also as shown, the plied yarns used in this embodiment of the invention are at least partially separated into their individual components and in some cases, the fibers from the individual components are also entangled with each other. This characteristic was not only unexpected, but it has been found to provide a unique and dramatic improvement in aesthetic and hand characteristics as compared with the untreated fabric, while retaining good fiber strength and FR characteristics as well.

One method of manufacturing the fabrics of the instant invention is as follows: a fabric as described above is woven or obtained. The fabric is then subjected to a high pressure fluid stream that is designed to soften and loft the fabric. One example of a fluid process that may be used is a hydraulic process of the variety described in commonly-assigned co-pending U.S. patent application Ser. No. 09/344,596 to Emery et al, filed Jun. 25, 1999, the disclosure of which is incorporated herein by reference. The type of fabric treatment and treatment parameters were selected to optimize the aesthetic characteristics of the fabric. Where multi-ply yarns are used, the high pressure stream also was surprisingly found to separate the plies from each other and to de-twist the yarns to some extent. It is believed that this lofting and ply separation dramatically enhanced the fabric hand and comfort, without adversely impacting fabric strength. The fabric can be treated on one or both fabric surfaces, depending on the desired end result. Also, if desired, one or more chemistries designed to enhance the fabric characteristics can be applied, either prior or subsequent to the hydraulic processing.

The fabric can be dyed to achieve an aesthetically appealing color, as desired. The dye process can be selected to optimize processing for the particular fiber content of the fabric and color desired. In the instant case, it has been found that using cationic dyes of the variety recommended by dye manufacturers for dyeing Nomex®) aramid fibers in a jet dye process at temperatures from about 220 degrees to about 270 degrees F. (and more preferably from about 250-270° F.) achieves a good color shade and fabrics having good colorfastness.

As noted above, chemistries can be applied to the fabric at any stage of the process, including before, during or after dyeing. In this way, additional characteristics such as moisture wicking, soil release, hand improvements, etc. can be obtained via chemical means. For example, it was surprisingly found that by applying an ethoxylated polyamide (traditionally used as a lubricant for nylon) and a high molecular weight ethoxylated polyester (typically used to enhance softness, wicking and stain release), fabrics having soil release and moisture transmission characteristics superior to those of commercially available fabrics were achieved at comparable levels of FR protection. Furthermore, it is believed that this superior soil release will also enhance the FR protection provided by the fabrics during their useful lives, since the fabrics of the invention will more readily release flammable soils such as oil and the like.

The fabrics are then desirably dried in a conventional manner, such as by running them through a heated tenter frame at a temperature of between about 325 and about 425 degrees F.

The fabrics of the invention have superior aesthetic characteristics (e.g. hand), as well as superior durability and performance (as evidenced by the test data below.) In addition, the fabrics had superior performance in the features correlating to enhanced wearer comfort. Furthermore, the fabrics had a unique surface characteristic, heretofore unachieved in FR fabrics.

EXAMPLES

Example A—A fabric was woven from 30/2 100% Nomex IIIA® air-jet spun yarns (95% Aramid, 3% Kevlar®, and 2% Nylon P-140 (from DuPont) with a twist multiple of 14 of the variety available from Pharr Yarns of McAdenville, N.C. in a 1×1 plain weave construction. The fabric was jet dyed in a conventional manner using cationic dyes of the variety conventionally recommended for the dyeing of the Nomex, and acid dyes of the variety commonly used to dye nylon (both of which will be readily appreciated by those of ordinary skill in the art. Dyeing was performed at approximately 266° F. for one hour. The fabric was then passed through a pad containing 1-½% Lurotex A-25 ethoxylated polyamide (distributed by BASF of Mount Olive, N.J.) and 1-½% Lubril QCX high molecular weight ethoxylated polyester manufactured by Tennessee Eastman (to facilitate stain release and wicking). The fabric was then dried in a conventional manner on a tenter frame at about 410° F. at a speed of approximately 25 yards per minute, after which the fabric was taken up for inspection. The finished product was nominally 68 ends per inch×44 picks per inch, and was 5.89 oz/sq yd in weight.

Example B—A fabric was woven in the same manner as Example A. However, prior to the jet dyeing step, it was run through a pad containing 1% Lubril QCX, a high molecular weight ethoxylated polyester of the variety designed to promote stain release (1% Lubril QCX from Tennessee Eastman), then the fabric was impacted by water jets on each of its face and back in the manner described in commonly-assigned co-pending U.S. patent application Ser. No. 09/344,596 to Emery et al, filed Jun. 25, 1999. The fabric was pulled through the pad and hydraulically treated at a speed of 30 yards per minute, and hydraulic treatment was performed using 1200 psi of the front side of the fabric and 800 psi on the opposite side of the fabric (manifold exit pressure). The water originated from a linear series of nozzles which were rectangular 0.015 inches wide, (filling direction)×0.010 inches high (warp direction) in shape and were equally spaced along the treatment zone. There were 40 nozzles per inch along the width of the manifold. The fabric traveled over a smooth stainless steel roll that was positioned 0.120 inches from the nozzles. The nozzles were directed downward about five degrees from perpendicular, and the water streams intersected the fabric path as the fabric was moving away from the surface of the roll. The tension in the fabric within the first treatment zone was set at about 45 pounds. In the second treatment zone, the opposite side of the fabric was treated with high pressure water that originated from a similar series of nozzles as described above. In this zone the water pressure was about 800 psig, the gap between the nozzles and the treatment roll was about 0.120 inches, and the nozzles were directed downward about five degrees from perpendicular. As before, the water streams intersected the fabric path as the fabric was moving away from the surface of the roll. The fabric tension between the treatment zones was set at about 85 pounds, and the fabric exit tension was set at about 90 pounds. The fabric was then dried to remove 95% of the moisture. The fabric was then dyed and finished in the same manner as Example A. It was surprisingly found that the hydraulic processing served to distinctly separate the plies of the multi-ply yarns and entangle yarns from different plies, in addition to expanding and opening the interstices of the fabric, and that this particular hydraulic treatment process primarily affected the yarns in the fabric warp.

Example C—A fabric was produced in the same manner as Example B, except the pressures used during hydraulic processing were 1100 on the front side of the fabric and 800 on the back side of the fabric.

Example D—A commercially available 6.39 oz/ sq yd plain woven 100% Nomex® IIIA aramid fabric of the variety typically used for coveralls or pants was obtained. It is believed that the fabric was finished with hand builders for added stiffness. The fabric had 26.46/2 MJS yarns (1.67 dpf) in the warp and 27.32/2 MJS yarns (1.76 dpf) in the filling. The fabric had approximately 66 ends per inch (epi) and 47 picks per inch (ppi), and had been dyed a navy color.

Example E is a commercially available 6.00 oz/sq yd plain woven 100% Nomex® IIIA aramid fabric. The fabric had 28.74/2 MJS yarns (1.72 dpf) in the warp and 28.85/2 MJS yarns (1.76 dpf) in the filling. The fabric had approximately 66 epi and 42 ppi, and had been dyed a spruce green color.

Example F is a commercially available 6.05 oz/sq yd plain woven 100% Nomex® IIIA aramid fabric. The fabric had 27.37/2 MJS yarns (1.71 dpf) in the warp and 28.41 MJS (1.74 dpf) yarns in the filling. The fabric had approximately 65 epi and 44 ppi. The fabric had been dyed a royal blue color.

Example G is a commercially available 6.39 oz/ sq yd plain woven 100% Nomex® IIIA aramid fabric of the variety typically used for outer clothing was obtained. It is believed that the fabric was finished with hand builders for added stiffness. The fabric had 26.46/2 MJS yarns (1.67 dpf) in the warp and 27.32/2 MJS yarns (1.76 dpf) in the filling. The fabric had approximately 66 ends per inch (epi) and 47 picks per inch (ppi), and had been dyed a navy blue color.

Example H was another commercially available FR fabric. The fabric was a 7 oz. 3×1 lefthand twill woven 100% cotton FR treated fabric having 92 epi×49 ppi, with 17.82/1 ring spun yarns in the warp and 12.08/1 RS yarns in the filling. The fabric had been dyed a navy blue color. It is believed that the FR treatment was achieved through a conventional ammonia treatment.

Example I was a commercially available 9 oz/sq yd 3×1 lefthand twill woven 100% cotton FR treated fabric. The fabric had 87 ends per inch and 50 picks per inch using 12.44/1 ring spun yarns in the warp and 8.53/1 ring spun yarns in the filling. The fabric had been dyed a khaki color. It is believed that the FR treatment was achieved through a conventional ammonia treatment.

Example J was another commercially available FR fabric. The fabric was a 7 oz. 88% cotton/12% nylon fabric. The fabric had 93 epi×50 ppi, with 18.12/1 RS yarns in the warp and 11.89/1 RS yarns in the filling. The fabric had been dyed a khaki color. It is believed that the FR treatment was achieved through a conventional ammonia treatment.

Example K was another commercially available FR fabric. The fabric was 9.68 oz. 88% cotton/12% nylon 3×1 twill woven fabric. The fabric had 92 epi×50 ppi, and 12.56 RS yarns in the warp and 8.58/1 RS yarns in the filling. The fabric had been dyed a navy blue color. It is believed that the FR treatment was achieved through a conventional ammonia treatment.

The fabrics were all subjected to a variety of tests as outlined below. The fabrics were tested in their as-produced form (unless otherwise specified in the test method), after 50 washes, and after 125 washes. All washes were performed in accordance with the Standard Formula Industrial Wash Method described below. The results of the tests are listed in the tables below.

Test Methods

Standard Formula Industrial Wash Method—

All washings were performed according to the following wash method: Garments were washed in a conventional industrial washer at 80% capacity for 12 minutes at 140° F., using the low water level and 8.0 oz of Choice chemical, which is commercially from Washing Systems, Inc. of Cincinnati, Ohio. The washing cycle was performed as follows: drop/fill/wash for 3 minutes at 140° F., low level water using 7.5 oz of Choice chemical; drop/fill/rinse for 2 minutes at 140° F., high level water, no chemical; drop/fill/rinse for 2 minutes at 80° F., high level water, no chemical; drop/fill/rinse for 2 minutes at 80° F., high level water, no chemical; drop/fill/wash for 4 minutes at 80° F., low level water using 0.3 oz acid sour; Extract water for 7 minutes at high speed.

Tensile Strength—

Tensile strengths in both the warp and filling directions were measured according to ASTM D1682-75. Generally speaking, in a protective product/protective garment end use, relatively high tensile strengths are desired since they positively impact durability. An exemplary industry specification for an industrial garment such as an overall or pant is 150 lbs in the warp and 100 lbs in the filling.

Tear Strength—

Tear strengths in both the warp and filling directions were measured according to ASTM D2262-83. Generally speaking, in a protective product/protective garment end use, relatively high tear strengths are considered to be desirable, since they correlate to durability. An exemplary industry specification for an overall or pant garment is a tear strength of 7.5 lbs in the warp direction and 7.5 lbs in the filling direction.

Pilling—

Pilling was tested after 30 minutes, 60 minutes, and 90 minutes according to ASTM D3512-82. A higher pilling rating indicates that the fabric has a greater resistance to pilling. A typical industry specification for an industrial garment such as an overall or a pant is 3.5-5 after 60 minutes.

Seam Slippage—

Seam slippage was measured in both the warp and filling directions according to ASTM D434-75. Generally speaking, a higher seam slippage will enhance product durability and an exemplary industry specific for a fabric to be used in an industrial garment such as a pant or overall would be 30 lbs in each direction.

Stoll Flat Abrasion—

Abrasion resistance was measured according to ASTM D3886-80. The maximum reading that the test will register is 1000.

Stretch—Stretch in each of the warp and filling directions was measured according to ASTM D3107-75.

Fray—

Fray was measured in both the warp and filling directions according to the following procedure, and the results recorded. A set of five (5) 4¼″ circle specimens of each sample are cut using a punch press machine, and are conditioned for one hour at 65% relative humidity ±5% at 70±5° F. (When cutting the samples, cut no closer to the selvage than 10% (±1%) of the fabric width, and mark the warp direction on each specimen.) A Random Tumble Pilling Machine available from Atlas, Inc. If the cork liner in the pilling apparatus has been used more than 3 times, place a new cork liner into test cylinders of the pilling tester making sure they are fitted properly to give a smooth joint. Put the five specimens from one sample into a single test cylinder. Make sure all specimens are in the path of the rotor. Up to six samples can be tested at a time. When the tester is loaded, start it and tumble the specimen for a period of 10 minutes (±30 seconds.) After this time period, remove the specimen from the tester. Measure the diameter in the direction of the marking (←→) to measure the warp through the marking (↑↓) to measure the filling using a ⅛^(th) inch graduated ruler R-9. Measure to first loose thread. The fraying value is expressed as a percentage and is calculated for both directions: % fray=(original length-tumbled length)/original length×100. (Note: original length=4.2) A lower fray value indicates a fabric has greater fray resistance. In particular, a lower warp fray value would suggest that a fabric would be more easily handled, thereby making product or garment manufacture more efficient.

Shrinkage—

Shrinkage in the warp and filling directions was measured according to AATCC Test Method 135-1995.

Appearance—

Wash appearance was rated according to AATCC Test Method 124-1996. The fabrics are rated on a scale from 1 to 5, with a higher rating indicating that the fabric retains a better appearance following washing.

Crease Retention—

Crease Retention was measured according to AATCC Test Method 39C-1984. Fabrics are rated on a scale from 1 to 5, with a higher rating indicating that a fabric has greater crease retention.

Soil Release—

The soil release properties of the fabrics were measured according to AATCC 130-1995 (corn oil), as follows: 0/1=Soiled prior to washing, tested after 1 wash. 4/5=Soiled after 4 washes, tested after 5 washes. 48/49=Soiled after 48 washes, tested after 49 washes. 48/50=Soiled after 48 washes, tested after 50 washes. 123/124=Soiled after 123 washes, tested after 124 washes. 123/125=Soiled after 123 washes, tested after 125 washes.

Vertical Wicking—

Wicking was measured using a vertical wicking test as follows. The test is used to determine the rate at which water will wick on test specimens suspended in water.

Equipment:

-   -   1. 500 ml Erlenmeyer flasks     -   2. Straight pins (approximately 3″ in length)     -   3. Food coloring (any color to make water level visible on         specimen)

Procedure:

1. Fill 500 ml Erlenmeyer flasks with 200 ml colored water (fill as many flasks as specimens to be tested).

-   -   2. A. Cut 6″×1″ strip of specimens to be tested (6″ length is         cut in the wale direction).     -    B. Pierce top edge of strip (approximately ⅛″-¼″ from top) with         long straight pin.     -   3. Suspend strip from pin in flask filled with 200 ml colored         water.     -   4. After 1 minute:         -   A. Remove strip from flask         -   B. Measure water level on strip in inches and record         -   C. Return strip to water     -   5. Repeat steps A., B., and C., from above at the following time         intervals; 3 minutes, 5 minutes, and each 5 minute interval         following until the water level reaches 6″ or 1 hour has         elapsed.

A higher score indicates the fabric has better wicking capability.

Drop Disappearance—

Wicking was also measured according to a drop disappearance test as follows. This test method is used to determine the efficiency of the fabric in transporting or wicking the moisture (such as an aqueous perspiration).

Equipment:

-   -   1. Straight medicine dropper     -   2. Stop watch     -   3. Distilled water     -   4. Embroidery hoops

Test Specimens:

A sample large enough to test three different areas is required (preferably full fabric width).

Procedure:

-   -   1. Place the sample in an embroidery hoop and pull tight. (Care         must be taken not to pull the sample too tight.)     -   2. The tip of the dropper should be one inch from the sample.         Allow one drop of water to fall onto the sample. Start timer         immediately. Watch the drop of water until it disappears and         stop the time. Record the time required for the drop to         disappear.     -   3. Repeat the above procedure on three different areas of each         sample. Test samples “as received” and after five washings and         tumble dryings, or as specified.

Report:

The average time required for the drop of water to disappear. A lower time indicates a fabric absorbs moisture more quickly.

Thickness—

Fabric thickness was measured according to ASTM D1777-1996.

Air Permeability—

Air permeability was measured according to AATCC Test Method 737-1996. In many applications (such as those where a wearer will wear the garment in a hot environment), higher air permeability will enhance the wearer's perception of the comfort of the garment. The air permeability is measured in cubic ft/min of air that travel through the fabric, with a higher number indicating that the fabric is more breathable.

Flammability (After Flame)—

Flammability (after flame) was measured according to National Fire Protection Agency (“NFPA”) Test Method 701-1989. The test indicates how long a fabric continues to burn after the flame has expired (with a lower number generally being preferable in an FR product.)

Flammability (After Glow)—

Flammability (after glow) was measured according to NFPA Test Method 701-1989. This test indicates how long a fabric continues to glow after the flame has expired (with a lower number generally being preferably in an FR product.

Flammability (Char Length)—

Char Length was measured according to NFPA Test Method 701-1989. A lower char length indicates a lesser tendency of a fabric to burn. Generally, to be suitable for an FR garment, a fabric must have a char length of less than 4 inches.

Thermal Protection Performance (TPP)—

Thermal Protection Performance was measured according to ASTM D4108-1996. A higher TPP value indicates that a fabric provides greater insulation.

Arc Thermal Protection Value (ATPV)—

Arc Thermal Protection Value was measured according to ASTM F 1959-1999. A minimum of twenty-one samples were tested for each fabric, and the results were averaged. A higher ATPV indicates that a fabric provides greater protection against electrical arc exposure.

Pyroman Test—

Burns were conducted on the Pyroman equipment (such as that available at the test labs at North Carolina State University) according to NFPA Test Method 2112 for 3 seconds. The % total body burn after each of the burns was recorded. A lower % body burn indicates the product is more protective of a wearer or user. A typical industry specification for a 3 second burn for a industrial garment (such as a pant or overall) is <50%.

Predicted Burn—

Also using the Pyroman equipment and test method described above, fabrics were tested at various flame exposure times, and the level of predicted burn (second degree, third degree, and total) were recorded. Several samples of each Example fabric were run.

Handle-O-Meter—

Handle-o-meter readings were measured in each of the warp and filling directions according to the following method, using Handle-o-meter model number 211-300 from Thwing Albert.

Using the Handle-O-Meter template (T-3), cut out three samples (face up). Be sure to cut samples at least 50 mm from selvage and/or 50 mm away from cut end of cloth. Avoid areas that have a fold or crease. Cut one from the left side, one from the center, and one from the right side. Label samples to indicate from where they were cut, and mark the warp and filling directions. Ensure the MODE selector is set in the TEST mode. If the Handle-O-Meter is not zeroed, unlock the ZERO control, adjust the knob until the indicator reads ±000, then re-lock the ZERO control. Set MODE selector to PEAK. Place swatch over slot extending across the platform, FACE UP. To check the warp, turn sample 90 degrees so that the sample top is on the left. To check the filling, place the sample in the machine with the sample top in the 12:00 position. Press START/RESET control. Test the samples, starting with the warp right, then test the filling right. Test the center and left side the same as above. Readings for standard should be recorded on 11ZHAND. Run Chart reading should be recorded on the correct style sheet and Data Document 11ZCTAN. When all 3 warps and all 3 fillings have been tested, average the warp and filling measurements and record. Repeat for additional set. A lower Handle-O-Meter reading indicates that the fabric is more flexible. Readings were recorded in units of grams-force.

Drape—

The drape coefficient was measured according to the following test process: Using an FRL® Drapemeter (of the variety described by Chu, C. C. , Cummings, C. L. and Teixeira, N. A., in “Mechanics of Elastic Performance of Textile Materials Part V: A Study of the Factors Affecting the Drape of Fabrics—The Development of a Drape Meter”, Textile Research Journal Vol 39 No. 8, 1950, pp. 539-548). This test is designed to determine the extent to which a fabric will deform when allowed to hang under its own weight, or by the ability of the fabric to drape by orienting itself into folds or pleats when acted upon by the force of gravity. The test used an FRL® Drapemeter, a uniform grade of tracing paper, a balance and scissors. The test specimens and tracing paper were conditioned to equilibrium and tested in the standard atmosphere of 65% relative humidity and 70° F. temperature. Moisture equilibrium shall be approached from the dry side (not moisture free.) Six test specimens (3 face up, and 3 face down), 10 inches in diameter were cut from the fabric. The specimens were taken from the right, center and left fabric areas, but no closer to the selvage than 1/10 of the fabric width. The specimens were marked as to face and back. A 10 inch diameter circle was cut from a uniform grade of tracing paper and it was weighed to the nearest milligram. The weight was recorded as W1. A 4 inch diameter circle (to represent the annular support ring) was cut and weighed to the nearest milligram. The weight was recorded as W2. A 10 inch diameter specimen was taken and a hole was made to mark the center of the test specimen. The specimen was placed on the support ring, and centered on the support. A sheet of tracing paper was placed on the clear top side of the Drapemeter. With the light source on, the paper was centered about the projected image of the fabric specimen and the outline of the shadow image was carefully traced on the paper. The traced image was cut out and the image paper was weighed to the nearest milligram, and recorded as W3.

The following calculation was made: Drape coefficient=[(W 3−W 2)/(W 1−W 2)]×100, where

-   -   W1=weight, 10 inch diameter paper, mg.     -   W2=weight, 4 inch diameter paper, mg     -   W3=weight, projected image, cut from paper used to obtain W1,         mg.

The six readings were averaged, and reported as the Drape Coefficient. If a side effect was noticed (back vs. face), sides are reported separately. A lower drape coefficient indicates that the fabric is more drapeable.

Ring Test Load—

Ring test load (i.e. Fabric handle by ring tensile) was measured according to the following test method. The test involves pulling the fabric through a ring at a set rate to determine the forces associated with friction and bending. A 10 inch diameter circle of the fabric to be tested was cut. The center of the circle was marked. The tensile tester was set up with a 38 mm diameter ring with a radius of 24 mm. The test speed was set at 10 inches/minute. A string was attached to a small fishhook, with the barb removed, and it was attached to the center of the fabric via the fishhook. The other end of the string was attached to the crosshead of the tensile tester. The tester was started and run until the fabric was pulled completely through the ring. The force required to pull the fabric through the ring and the modulus of the initial folding of the fabric as it approached the ring were recorded. A lower ring test load value indicates that a fabric is more supple and flexible.

Kawabata Testing—

A variety of characteristics were measured using the Kawabata Evaluation System (“Kawabata System”). The Kawabata System was developed by Dr. Sueo Kawabata, Professor of Polymer Chemistry at Kyoto University in Japan, as a scientific means to measure, in an objective and reproducible way, the “hand” of textile fabrics. This is achieved by measuring basic mechanical properties that have been correlated with aesthetic properties relating to hand (e.g. smoothness, fullness, stiffness, softness, flexibility, and crispness), using a set of four highly specialized measuring devices that were developed specifically for use with the Kawabata System. These devices are as follows:

Kawabata Tensile and Shear Tester (KES FB1)

Kawabata Pure Bending Tester (KES FB2)

Kawabata Compression Tester (KES FB3)

Kawabata Surface Tester (KES FB4)

KES FB1 through 3 are manufactured by the Kato Iron Works Col, Ltd., Div. Of Instrumentation, Kyoto, Japan. KES FB4 (Kawabata Surface Tester) is manufactured by the Kato Tekko Co., Ltd., Div. Of Instrumentation, Kyoto, Japan. In each case, the measurements were performed according to the standard Kawabata Test Procedures, with four 8-inch×8-inch samples of each type of fabric being tested, and the results averaged. Care was taken to avoid folding, wrinkling, stressing, or otherwise handling the samples in a way that would deform the sample. The fabrics were tested in their as-manufactured form (i.e. they had not undergone subsequent launderings.) The die used to cut each sample was aligned with the yarns in the fabric to improve the accuracy of the measurements.

Shear Measurements

The testing equipment was set up according to the instructions in the Kawabata manual. The Kawabata shear tester (KES FB1) was allowed to warm up for at least 15 minutes before being calibrated. The tester was set up as follows:

Sensitivity: 2 and ×5

Sample width: 20 cm

Shear weight: 195 g

Tensile Rate: 0.2 mm/s

Elongation Sensitivity: 25 mm

The shear test measures the resistive forces when the fabric is given a constant tensile force and is subjected to a shear deformation in the direction perpendicular to the constant tensile force.

Mean Shear Stiffness (G) [gf/(cm-deg)].

Mean shear stiffness was measured in each of the warp and filling directions. A lower value for shear stiffness is indicative of a more supple hand.

Shear Hysteresis at 0.5°, 2.5° and 50°—(2HG05, 2HG25, and 2HG50, respectively) [gf/cm]—

A lower value indicates that the fabric recovers more completely from shear deformation. This correlates to a more supple hand.

Residual Shear Angle at 0.5°, 2.5°, and 5.0° (RG05, RG25, and RG50, respectively.) [degrees]

The lower the number, the more “return energy” required to return the fabric to its original orientation.

Four samples were taken in each of the warp and filling directions, averaged, and are listed below.

Bending Measurements

Bending Stiffness (B)—

A lower value means a fabric is less stiff.

Bending hysteresis at 0.5°, 1.0°, and 1.5° (2HB05, 2HB10, 2HB15)

Mean bending stiffness per unit width at K=0.5, 1.0 and 1.5 cm⁻¹ [gf-cm/cm]. Bending stiffness was measured in each of the warp and filling. A lower value means the fabric recovers more completely from bending, and has a softer, more supple hand.

Residual Bending at 0.5°, 1.0°, and 1.5°—(RB05, RB10, RB15)

Residual bending curvature at K=0.5, 1.0 and 1.5 cm⁻¹. A lower residual bending curvature indicates that a fabric is stiffer (less supple).

Compression Analysis

The testing equipment was set up according to the instructions in the Kawabata manual. The Kawabata Compression Tester (KES FB3) was allowed to warm up for at least 15 minutes before being calibrated. The tester was set up as follows:

Sensitivity: 2 and ×5

Stroke: 5 mm

Compression Rate: 1 mm/50 s

Sample Size: 20×20 cm

The compression test measured the resistive forces experienced by a plunger having a certain surface area as it moves alternately toward and away from a fabric sample in a direction perpendicular to the fabric. The test ultimately measures the work done in compressing the fabric (forward direction) to a preset maximum force and the work done while decompressing the fabric (reverse direction).

Percent compressibility at 0.5 grams (COMP05)

The higher the measurement, the more compressible the fabric.

Maximum Thickness (TMAX)—

Thickness [mm] at maximum pressure (nominal is 50 gf/cm²). A higher TMAX indicates a loftier fabric.

Minimum Thickness (TMIN)

Thickness at 0.5 g/sq cm. More is generally considered to be better. A higher TMIN indicates a loftier fabric.

Minimum Density—

Density at TMIN (DMIN). Less is generally considered to be better) T_(min)[g/cm³]

Maximum Density—

Density at TMAX (DMAX)—T_(max)[g/cm³] A lower value is generally considered to be better.

Thickness Change During Compression (TDIFF)—

Higher indicates a loftier fabric.

Compressional Work per Unit Area (WC)

Energy to compress fabric to 50 gf/cm²[gf-cm/cm²]. More is generally considered to be better.

Decompressional Work per Unit Area (WC′)

This is an indication of the resilience of the fabric. A larger number indicates more resilience (i.e. a springier hand), which is generally considered to be better.

Linearity of Compression—0.5 grams-(LC05)—

Compares compression work with the work along a hypothetical straight line from (X₀, y(X₀)) to (X_(max), y(X_(max))) The closer to linear, the more consistent the fabic is.

% Compression Resilience—(RC)

Higher means recovers better from compression.

Surface Analysis

The testing equipment was set up according to the instructions in the Kawabata Manual. The Kawabata Surface Tester (KES FB4) was allowed to warm up for at least 15 minutes before being calibrated. The tester was set up as follows:

Sensitivity 1: 2 and ×5

Sensitivity 2: 2 and ×5

Tension Weight: 480 g

Surface Roughness Weight: 10 g

Sample Size: 20×20 cm

The surface test measures frictional properties and geometric roughness properties of the surface of the fabric.

Coefficient of Friction—(MIU)

Mean coefficient of friction [dimensionless]. This was tested in each of the warp and filling directions. A higher value indicates that the surface consists of more fiber ends and loops, which gives the fabric a soft, fuzzy hand.

Mean Deviation of Coefficient of Friction (MMD)—

Indicates the level of consistency of the coefficient of friction.

Surface roughness (SMD) Mean deviation of the displacement of contactor normal to surface [microns]. Indicative of how rough the surface of the fabric is. A lower value indicates that a fabric surface has more fiber ends and loops that give a fabric a softer, more comfortable hand.

Tensile Analysis

Tensile Energy (WT)

was measured in each of the warp and filling directions. A lower tensile energy generally indicates the fabric has “give” to it and is more extensible, which would be expected to be indicative of greater fabric comfort.

Linearity of Extension (LT)—

Dimensionless—Indicates consistency of extension.

Tensile Resiliency(RT)—

Measured in percent. Indicates ability of fabric to recover from tensile stretch.

Percent Extensibility (EMT)—

Measured in each of the warp and filling directions. A higher number indicates a fabric has a greater stretch property. (This is a static profile.) TABLE A Tensile Warp Tensile Fill (LBS) (LBS) 0 50 100 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 236 215 227 130 140 140 Example B 221 204 206 131 142 146 Example C — — — — — — Example D 235 213 224 166 150 159 Example E 212 199 212 133 135 149 Example F 231 210 209 152 139 138 Example G 235 213 224 166 150 159 Example H 78 78 86 40 44 66 Example I 139 137 123 83 75 97 Example J 87 84 77 59 59 65 Example K 139 140 106 84 87 90

TABLE B Tear Warp Tear Fill (LBS) (LBS) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 15.4 10.6 8.9 12.7 7.2 6.5 Example B 13.2 8.7 8.6 10.3 6.7 6.7 Example C — — — — — — Example D 14.3 9.1 9.1 9.8 7.6 6.3 Example E 13.4 9.4 10.2 8.1 7.3 6.7 Example F 9.7 8.4 8.7 8.2 5.9 6.3 Example G 14.3 9.1 9.1 9.8 7.6 6.3 Example H 7.7 6.4 4.3 8.0 7.1 3.5 Example I 8.2 4.2 4.4 7.8 4.9 4.9 Example J 8.2 4.1 3.9 7.8 4.3 3.6 Example K 7.3 4.4 3.6 9.2 4.7 5.1

TABLE C Pilling - 30 minutes Pilling - 60 minutes (Rated 1-5) (Rated 1-5) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 4.0 5.0 5.0 4.0 5.0 5.0 Example B 4.0 5.0 5.0 4.0 5.0 5.0 Example C — — — — — — Example D 4.3 4.8 5.0 4.3 4.8 5.0 Example E 4.0 5.0 4.5 4.0 4.5 5.0 Example F 4.0 5.0 5.0 4.0 5.0 5.0 Example G 4.3 4.8 5.0 4.3 4.8 5.0 Example H 4.5 5.0 4.0 4.5 5.0 2.5 Example I 4.5 5.0 5.0 4.5 5.0 5.0 Example J 4.5 4.5 5.0 4.5 4.5 4.0 Example K 4.5 5.0 5.0 4.5 5.0 5.0

TABLE D Stoll Flat Abrasion (Cycles until Pilling - 90 minutes sample falls apart - Test (Rated 1-5) Maximum is 1000 cycles) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 4.0 5.0 5.0 1000 1000 1000 Example B 4.0 5.0 5.0 1000 1000 1000 Example C — — — — — — Example D 4.3 5.0 4.8 1000 1000 1000 Example E 4.0 5.0 4.5 1000 1000 1000 Example F 4.0 5.0 5.0 1000 1000 1000 Example G 4.3 5.0 4.8 1000 1000 1000 Example H 4.5 4.5 2.0 1000 1000 1000 Example I 4.5 5.0 5.0 1000 1000 1000 Example J 4.5 3.5 4.5 1000 1000 1000 Example K 4.5 5.0 5.0 1000 1000 1000

TABLE E Seam Slippage - Warp Seam Slippage - Filling (LBS) (LBS) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 50 46.6 43.7 45 44 43.2 Example B 58 49 50 47 47 45 Example C — — — — — — Example D 48 47 45 48 47 45 Example E 55 48 46 55 48 46 Example F 48 45 51 48 45 51 Example G 48 47 45 48 47 45 Example H 48 43 42 43 43 41 Example I 53 40 43 49 43 40 Example J 44 38 42 47 40 43 Example K 40 47 49 35 41 46

TABLE F Warp Stretch Fill Stretch (%) (%) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 3.80 6.30 7.50 1.25 3.80 3.80 Example B 5.00 7.50 7.50 2.50 2.50 3.80 Example C — — — — — — Example D 5.00 7.50 7.50 2.50 3.80 3.80 Example E 7.50 7.50 7.50 3.80 3.80 3.80 Example F 3.80 6.30 6.30 2.50 3.80 5.00 Example G 5.00 7.50 7.50 2.50 3.80 3.80 Example H 5.00 7.50 10.00 6.30 10.00 10.00 Example I 6.30 7.50 7.50 5.00 7.50 10.00 Example J 8.80 8.80 7.50 7.50 10.00 10.00 Example K 6.00 8.80 6.30 5.00 7.50 7.50

TABLE G Fray Warp Fray Fill (%) (%) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 13.80 2.38 10.95 26.90 11.90 21.43 Example B 4.80 2.86 2.38 9.50 8.57 10.48 Example C — — — — — — Example D 19.30 3.34 14.04 4.70 4.05 14.28 Example E 13.40 8.60 7.62 16.20 18.00 20.00 Example F 13.80 21.43 10.95 4.70 19.52 19.05 Example G 19.30 3.34 14.04 4.70 4.05 14.28 Example H 23.00 4.76 15.71 17.00 13.33 7.62 Example I 2.40 18.10 15.24 2.40 6.19 4.76 Example J 7.10 17.14 16.67 21.40 7.62 1.48 Example K 2.40 11.90 2.86 4.80 4.29 11.90

TABLE H Shrinkage Warp Shrinkage Filling (%) (%) 50 125 0 50 125 Parameter 0 Washes Washes Washes Washes Washes Washes Example A 2.1 0.0 0.5 0.6 0.3 0.5 Example B 2.7 0.6 0.3 0.8 0.3 0.1 Example C — — — — — — Example D 1.9 0.3 0.8 1.2 0.6 0.0 Example E 1.5 0.9 1.0 0.7 0.5 0.9 Example F 1.4 0.3 0.1 1.4 0.7 0.4 Example G 1.9 0.3 0.8 1.2 0.6 0.0 Example H 0.6 0.7+ 0.3 3.1 0.2+ 0.2 Example I 0.9 0.1 0.5 0.0 0.6 0.1 Example J 0.6 1.1 0.8 3.2 0.6 0.2 Example K 3.7 1.0 0.2 0.0 1.0 0.5

TABLE I Appearance Crease Retention (Rated 1-5) (Rated 1-5) 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example A 3.5 4.5 4.5 4.0 5.0 5.0 Example B 3.5 4.0 4.5 4.0 5.0 5.0 Example C — — — — — — Example D 3.5 3.8 3.8 4.0 5.0 5.0 Example E 4.0 4.0 4.5 4.0 5.0 5.0 Example F 3.0 4.0 4.0 4.0 5.0 5.0 Example G 3.5 3.8 3.8 4.0 5.0 5.0 Example H 3.0 3.5 3.5 4.0 5.0 5.0 Example I 3.0 3.5 3.5 4.0 5.0 5.0 Example J 3.5 3.5 3.5 4.0 5.0 5.0 Example K 3.0 4.0 3.5 4.0 5.0 5.0

TABLE J Soil Release (Rated 1-5) Parameter 0/1 4/5 48/49 48/50 123/124 123/125 Example A 2.5 3.5 4.5 2.5 3.5 4.5 Example B 3.3 3.0 4.0 4.5 4.0 5.0 Example C — — — — — — Example D 2.0 1.3 2.4 3.6 1.9 3.9 Example E 1.5 2.0 3.0 3.7 2.5 3.0 Example F 2.0 1.0 2.6 3.4 2.3 4.3 Example G 2.0 1.3 2.4 3.6 1.9 3.9 Example H 1.0 1.0 1.5 2.6 1.3 4.0 Example I 1.0 1.0 1.5 3.9 1.5 4.3 Example J 1.0 1.0 3.1 4.3 3.8 4.5 Example K 1.0 1.0 1.6 1.8 1.0 3.5

TABLE K Vertical Wicking - 15 Drop Disappearance minutes (inches) (seconds) 0 50 125 50 125 Parameter Washes Washes Washes 0 Washes Washes Washes Example A 5.9 4.7 5.1 <1 sec 1.7 2.5 Example B 6.8 4.7 4.7 <1 sec 2.0 1.7 Example C — — — — — — Example D 4.6 5.3 5.8 2.2 2.7 4.4 Example E 4.9 5.3 5.9 3.0 3.8 3.9 Example F 5.6 6.5 6.6 5.3 4.7 4.0 Example G 4.6 5.3 5.8 2.2 2.7 4.4 Example H 5.1 6.4 6.4 3.1 0.4 0.8 Example I 5.1 5.4 5.0 2.9 0.7 0.5 Example J 5.2 6.6 6.6 1.5 0.3 0.4 Example K 4.7 5.5 5.1 2.5 0.6 0.7

TABLE L Thickness Air Permeability (mm) (cfm) 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example A 19.40 22.32 22.01 84.4 61 58.8 Example B 22.48 25.63 25.16 77.6 57.6 55.3 Example C — — — — — — Example D 19.87 22.10 21.85 47.3 39.5 42.8 Example E 20.78 21.33 21.88 80.6 83.4 84.6 Example F 21.25 21.63 22.13 47.1 78.3 80.2 Example G 19.87 22.10 21.85 47.3 39.5 42.8 Example H 16.5 25.13 25.63 54.1 53.8 64.7 Example I 22.33 29.19 28.88 19.6 10.6 10.9 Example J 19.65 26.32 26.13 37.6 55.2 58.1 Example K 23.65 29.69 30.44 26.07 10 9.84

TABLE M Flammability- After Flame Flammability- After Glow (seconds) (seconds) 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example A <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example B <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example C — — — — — — Example D <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example E <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example F <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example G <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example H <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example I <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example J <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec Example K <1 sec <1 sec <1 sec <1 sec <1 sec <1 sec

TABLE N Flammability- Char Length Thermal Protection (inches) Performance (TPP) 0 50 (calories/cubic cm) Parameter Washes Washes 125 Washes 0 Washes Example A 1.9 2.9 3.1 8.83 Example B 2.3 3.1 2.3 9.21 Example C — — — — Example D 3.8 2.3 2.4 9.19 Example E 3.9 2.1 2.0 — Example F 3.6 2.3 2.8 9.25 Example G 3.8 2.3 2.1 9.19 Example H 3.1 1.9 2.4 7.48 Example I 2.5 1.9 2.4 9.53 Example J 3.2 2.9 3.8 8.90 Example K 3.4 2.6 2.1 —

TABLE O Arc Thermal Protection Value (ATPV) (calories/cm²) Pyroman Parameter All are washed as part of test 3 seconds Example A 6.1 — Example B 6.0 28 Example C — — Example D 5.7 <50R Example E — <50R Example F 5.6 <50R Example G 5.7 <50R Example H 6.0R <50R Example I 7.9R <50R Example J 7.3R <50R Example K 11.2R <50R R = recorded in the literature

TABLE P Predicted Burn Flame Second Example Exposure (sec) Degree Third Degree Total Example B 4.00 40.98 8.20 49.18 Sample 1 Example B 4.00 45.08 8.20 53.28 Sample 2 Example B 4.00 41.80 9.02 50.82 Sample 3 Average 42.62 8.47 51.09 Example B 3.00 18.85 6.56 25.41 Sample 1 Example B 3.00 22.13 6.56 28.69 Sample 2 Example B 3.00 23.77 6.56 30.33 Sample 3 Average 21.59 6.56 28.14 Example B 3.50 28.69 6.56 28.14 Sample 1 Example B 5.00 39.34 22.95 62.30 Sample 1 Example B 5.00 43.44 18.03 61.48 Sample 2 Example B 5.00 42.62 20.49 63.11 Sample 3 Average 41.80 20.49 62.29

TABLE Q Handle-O-Meter- Warp Handle-O-Meter-Filling (grams force) (grams force) Parameter 0 Washes 0 Washes Example A 33 27 Example B 34 26 Example C — — Example D 97 70 Example E 109 79 Example F 124 52 Example G 97 70 Example H 41 21 Example I 192 182 Example J 32 18 Example K 209 264

TABLE R Drape Coefficient Ring Test Load (0-100) (lbs.) 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example A 33.4 26.86 26.50 72.64 59.25 72.36 Example B 30.90 28.46 24.17 90.80 66.93 102.10 Example C — — — — — — Example D 64.90 34.61 31.20 208.84 90.25 83.71 Example E 70.60 31.08 — 249.70 83.28 — Example F 65.20 33.47 30.54 340.50 93.00 89.86 Example G 64.90 34.61 31.20 208.84 80.25 83.71 Example H 39.3 38.8 31.7 140.74 120.190 121.277 Example I 74.0 56.5 47.3 612.90 541.826 297.478 Example J 34.4 37.3 35.9 136.20 97.203 100.951 Example K 80.3 53.0 51.2 862.60 352.747 392.280

TABLE S Bending Stiffness (B) Bending Stiffness (B) Warp Direction Filling Direction 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example A 0.140 0.091 0.085 0.101 0.083 0.088 Example B 0.15 0.088 0.084 0.11 0.090 0.089 Example C — — — — — — Example D 0.766 0.130 0.101 0.418 0.112 0.087 Example E 0.723 0.120 0.112 0.371 0.085 0.073 Example F 0.903 0.270 0.260 0.324 0.090 0.081 Example G 0.766 0.130 0.101 0.418 0.112 0.087 Example H 0.21 0.162 0.119 0.13 0.084 0.080 Example I 1.04 0.359 0.337 1.06 0.214 0.214 Example J 0.17 0.173 0.169 0.12 0.083 0.092 Example K 1.50 0.362 0.398 1.66 0.226 0.257

TABLE T % Compressibility (Comp 05) 0 50 Parameter Washes Washes 125 Washes Example A 40.680 42.808 42.141 Example B 40.126 45.044 42.182 Example C 42.459 44.727 42.398 Example D 33.454 40.529 38.959 Example E 34.717 41.842 40.427 Example F 36.736 41.994 42.182 Example G 33.454 40.529 38.959 Example H 40.432 39.837 34.407 Example I 31.886 29.658 25.763 Example J 39.871 37.860 33.236 Example K 32.183 33.251 27.035

TABLE U Shear Stiffness (G) Shear Stiffness (G) Warp Filling 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example A 0.7770 0.658 0.592 0.6357 0.489 0.435 Example B 0.9590 0.739 0.612 0.7833 0.583 0.490 Example C 0.9260 0.701 0.653 0.7683 0.569 0.521 Example D 3.4670 1.068 0.968 3.3963 1.028 0.871 Example E 2.4437 0.692 0.633 2.2013 0.615 0.568 Example F 2.2210 0.512 0.498 2.0490 0.470 0.403 Example G 2.9357 1.068 0.968 2.7140 1.028 0.871 Example H 0.7547 0.838 0.835 0.6633 0.829 0.734 Example I 2.7373 2.763 2.575 2.6953 2.773 2.662 Example J 0.9037 0.845 0.868 0.8197 0.772 0.757 Example K 3.0097 2.905 3.268 2.9207 3.096 3.307

TABLE V Coefficient of Friction Coefficient of Friction (MIU) Warp (MIU) Filling 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example 0.193000 0.212 0.214 0.217667 0.222 0.227 A Example 0.213667 0.217 0.216 0.224667 0.224 0.227 B Example 0.209667 0.217 0.223 0.219667 0.229 0.233 C Example 0.189333 0.211 0.214 0.199667 0.218 0.233 D Example 0.187000 0.202 0.208 0.187000 0.225 0.227 E Example 0.209667 0.199 0.210 0.221667 0.212 0.219 F Example 0.185667 0.211 0.214 0.201667 0.218 0.233 G Example 0.217333 0.231 0.228 0.225667 0.257 0.250 H Example 0.178333 0.221 0.226 0.194667 0.246 0.242 I Example 0.217000 0.231 0.247 0.233333 0.253 0.273 J Example 0.177000 0.242 0.231 0.198333 0.252 0.241 K

TABLE W WT Warp WT Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 10.521 12.639000 13.34970 5.375 7.151300 7.28630 Example B 10.668 13.716700 13.59600 5.444 7.536700 7.66530 Example C 11.006 13.672700 13.76430 5.578 7.473700 7.68270 Example D 9.262 13.063700 12.90800 4.917 7.490700 7.30570 Example E 8.198 11.222700 11.92700 5.533 6.780700 6.95670 Example F 10.673 13.130000 13.12900 6.191 8.625300 8.51500 Example G 10.931 12.657700 13.06700 6.012 6.696000 7.33100 Example H 9.494 12.851700 14.12670 15.510 18.642000 20.06800 Example I 13.509 13.933700 15.92600 13.516 16.307700 16.75200 Example J 12.471 13.630700 14.99430 17.192 18.972700 19.43500 Example K 14.217 14.322700 17.07100 11.616 16.035300 16.29770

TABLE X % Extensibility (EMT) % Extensibility (EMT) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 5.8950 8.562 8.977 2.9100 4.808 4.575 Example B 6.2217 8.905 8.788 2.9967 4.982 4.797 Example C 5.9317 9.125 8.725 3.3033 5.045 4.703 Example D 5.1833 8.161 8.024 2.9167 4.455 4.553 Example E 3.9750 7.585 7.320 3.0500 4.508 3.862 Example F 6.0233 8.135 8.160 3.6250 5.608 5.385 Example G 5.8650 8.161 8.024 3.1783 4.455 4.553 Example H 6.3400 8.465 9.192 9.8617 12.215 13.150 Example I 7.8883 8.083 8.982 6.6200 9.277 9.210 Example J 7.3300 8.942 9.871 11.3317 12.400 12.537 Example K 7.6650 8.323 9.702 6.0950 9.250 8.527

TABLE Y Bending Hysteresis (2HB05) Bending Hysteresis (2HB05) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.07200 0.045330 0.04067 0.06400 0.052333 0.04433 Example B 0.07400 0.046670 0.04600 0.06967 0.045667 0.04400 Example C 0.07133 0.047000 0.04900 0.05567 0.055333 0.03900 Example D 0.25633 0.061670 0.05067 0.20100 0.059667 0.04500 Example E 0.22133 0.069670 0.05800 0.13933 0.054667 0.04333 Example F 0.28000 0.165670 0.12800 0.14500 0.052000 0.04300 Example G 0.25667 0.078330 0.05867 0.22467 0.076333 0.05100 Example H 0.11900 0.113330 0.09300 0.05200 0.049333 0.05200 Example I 0.30133 0.208670 0.19967 0.22333 0.135667 0.14833 Example J 0.10467 0.114330 0.15000 0.06200 0.051333 0.06733 Example K 0.39700 0.244330 0.35900 0.32400 0.152333 0.19800

TABLE Z Bending Hysteresis (2HB10) Bending Hysteresis (2HB10) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.07467 0.056330 0.05033 0.06500 0.064000 0.06033 Example B 0.08267 0.058000 0.05600 0.07400 0.059333 0.05967 Example C 0.08067 0.058670 0.06133 0.07000 0.072000 0.01533 Example D 0.38700 0.078330 0.06567 0.26567 0.077333 0.05800 Example E 0.30867 0.089000 0.07633 0.18467 0.067667 0.05433 Example F 0.39633 0.223330 0.18700 0.17433 0.067667 0.05633 Example G 0.33067 0.098000 0.07333 026167 0.096000 0.06500 Example H 0.11700 0.146330 0.11600 0.05967 0.058333 0.06033 Example I 0.37533 0.295330 0.28667 0.32200 0.175667 0.18533 Example J 0.37533 0.156330 0.17933 0.06100 0.061333 0.07767 Example K 0.49600 0.332000 0.44800 0.44433 0.189667 0.24333

TABLE AA Bending Hysteresis (2HB15) Bending Hysteresis (2HB15) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.07567 0.067670 0.05967 0.06333 0.074333 0.07000 Example B 0.08367 0.068670 0.06200 0.06567 0.068000 0.07400 Example C 0.08433 0.068000 0.07167 0.08400 0.084667 0.06267 Example D 0.40967 0.092670 0.07967 0.27933 0.099333 0.07400 Example E 0.31733 0.110670 0.09600 0.19767 0.078667 0.06467 Example F 0.42800 0.272670 0.24033 0.18567 0.082000 0.07067 Example G 0.32300 0.116330 0.08800 0.25333 0.119333 0.07967 Example H 0.11133 0.179330 0.13333 0.05133 0.070000 0.06833 Example I 0.39967 0.381670 0.37400 0.34700 0.218333 0.22733 Example J 0.10467 0.187330 0.19333 0.05667 0.073333 0.08333 Example K 0.51467 0.422330 0.48267 0.48967 0.233333 0.29467

TABLE BB Residual Bending (RB05) Residual Bending (RB05) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.52267 0.499330 0.48167 0.65300 0.577000 0.50700 Example B 0.48467 0.528670 0.55067 0.67033 0.554670 0.49233 Example C 0.46500 0.539670 0.53133 0.42467 0.545000 0.48533 Example D 0.28033 0.562670 0.49800 0.43867 0.556000 0.52333 Example E 0.30667 0.590000 0.51667 0.37733 0.637670 0.59033 Example F 0.32100 0.612670 0.49200 0.45633 0.572000 0.53333 Example G 0.42333 0.628330 0.58600 0.60833 0.655000 0.58133 Example H 0.57333 0.699000 0.78633 0.41467 0.587330 0.64667 Example I 0.28500 0.582330 0.59933 0.21333 0.633000 0.69267 Example J 0.63133 0.665000 0.88633 0.53767 0.617330 0.73233 Example K 0.26100 0.684000 0.89667 0.19100 0.675000 0.76933

TABLE CC Residual Bending (RB10) Residual Bending (RB10) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.53933 0.621330 0.58967 0.65467 0.707000 0.68233 Example B 0.54333 0.660330 0.66467 0.71600 0.715330 0.66367 Example C 0.52233 0.675330 0.66500 0.52167 0.714330 0.63567 Example D 0.42067 0.714000 0.64367 0.57767 0.720000 0.67600 Example E 0.42767 0.748330 0.68233 0.50067 0.789670 0.74600 Example F 0.44433 0.827670 0.71633 0.54300 0.747000 0.69767 Example G 0.54467 0.783330 0.73167 0.70667 0.825330 0.74033 Example H 0.56300 0.901670 0.97667 0.47300 0.692670 0.75300 Example I 0.35800 0.824330 0.85567 0.30567 0.820330 0.86333 Example J 0.63833 0.903000 1.05867 0.52967 0.738330 0.83967 Example K 0.33100 0.924000 1.12200 0.26533 0.839670 0.94600

TABLE DD Residual Bending (RB15) Residual Bending (RB15) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.54700 0.747000 0.70167 0.62800 0.823000 0.79767 Example B 0.55100 0.782000 0.74033 0.62467 0.824000 0.82500 Example C 0.54800 0.784000 0.77767 0.62800 0.845330 0.77333 Example D 0.44433 0.844000 0.78300 0.60500 0.925330 0.85667 Example E 0.43867 0.923330 0.85833 0.53367 0.920670 0.88400 Example F 0.47800 1.008000 0.92300 0.56967 0.903000 0.87533 Example G 0.53167 0.928330 0.88167 0.68467 1.021330 0.90500 Example H 0.53633 1.102670 1.12200 0.40333 0.826000 0.86167 Example I 0.38467 1.064670 1.11433 0.32767 1.021000 1.05967 Example J 0.63400 1.079000 1.13933 0.49167 0.881000 0.90800 Example K 0.34567 1.174670 1.21867 0.29800 1.033000 1.14533

TABLE EE Maximum Thickness (Tmax) (mm) Maximum Density (DENMAX) Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.536333 0.586000 0.58567 0.371000 0.367000 0.36700 Example B 0.582333 0.666333 0.67167 0.350333 0.333000 0.32967 Example C 0.588000 0.662000 0.64767 0.349000 0.333667 0.34000 Example D 0.551000 0.588000 0.57867 0.381333 0.377000 0.38367 Example E 0.555667 0.577333 0.57500 0.361000 0.351333 0.35067 Example F 0.585667 0.582333 0.59133 0.352667 0.362000 0.35567 Example G 0.543667 0.577667 0.56533 0.394667 0.381000 0.39200 Example H 0.496000 0.633667 0.65533 0.462333 0.377333 0.34600 Example I 0.604000 0.716000 0.75100 0.530000 0.465000 0.43633 Example J 0.518333 0.690333 0.67833 0.451000 0.34433 0.34367 Example K 0.631000 0.752667 0.79700 0.534333 0.448333 0.43000

TABLE FF Minimum Thickness Minimum Density (Tmin) (mm) (DENMIN) Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.904330 1.025000 1.01233 0.220333 0.210000 0.21233 Example B 0.972670 1.212670 1.16200 0.209667 0.182667 0.19067 Example C 1.022330 1.197330 1.12367 0.201000 0.184333 0.19567 Example D 0.794330 0.987670 0.96000 0.264667 0.224333 0.23133 Example E 0.852000 0.992670 0.96533 0.235667 0.204667 0.20900 Example F 0.927330 1.004330 1.02233 0.223000 0.210000 0.20600 Example G 0.853330 0.973000 0.91500 0.251000 0.226667 0.24267 Example H 0.833000 1.054670 0.99900 0.275000 0.227333 0.22700 Example I 0.887670 1.018000 1.01133 0.361000 0.326667 0.32400 Example J 0.862670 1.111000 1.01600 0.271333 0.214000 0.22933 Example K 0.930670 1.127670 1.09167 0.362333 0.299333 0.31367

TABLE GG Compressional Work per Linearity of Unit Area (WC) Compression (LC 05) Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.300000 0.407000 0.38300 0.32533 0.369670 0.35933 Example B 0.385000 0.517330 0.48633 0.39733 0.379670 0.39833 Example C 0.411000 0.510670 0.45800 0.38033 0.381670 0.38533 Example D 0.203670 0.359330 0.33200 0.33633 0.362330 0.34967 Example E 0.215000 0.357330 0.32633 0.29533 0.345670 0.33533 Example F 0.282330 0.368330 0.38300 0.33233 0.347330 0.35733 Example G 0.254670 0.386670 0.34100 0.32767 0.393000 0.39200 Example H 0.286670 0.370000 0.33900 0.33933 0.353000 0.39667 Example I 0.257670 0.322330 0.28767 0.36767 0.432000 0.44000 Example J 0.299000 0.401330 0.33233 0.34933 0.382670 0.39833 Example K 0.265670 0.362330 0.31333 0.35433 0.389670 0.42667

TABLE HH Decompressional Work Compression per Unit Area (WCPrime) Resilience (RC) % Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.153333 0.177000 0.16300 51.2443 43.446300 42.50530 Example B 0.209667 0.219667 0.20800 53.0833 42.429700 42.76830 Example C 0.218000 0.223000 0.19767 54.3957 43.721000 43.21800 Example D 0.115333 0.155667 0.14267 56.6363 43.275300 43.03830 Example E 0.117333 0.159000 0.14233 54.5963 44.414000 43.63930 Example F 0.137667 0.165333 0.16633 48.9260 44.944300 43.43170 Example G 0.132333 0.159667 0.13967 51.8593 41.299000 40.81070 Example H 0.126667 0.130333 0.12000 44.2787 35.217700 35.42070 Example I 0.125000 0.105333 0.10333 48.4010 32.861000 35.95200 Example J 0.129333 0.132667 0.11467 43.2660 33.014300 34.47900 Example K 0.123333 0.122667 0.11233 46.2480 33.939000 35.80870

TABLE II Thickness Change During Weight (g) Compression (Tdiff) (mm) Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 19.9167 21.508300 21.50000 0.36833 0.439000 0.42667 Example B 20.4083 22.175000 22.15000 0.39033 0.546670 0.49033 Example C 20.5333 22.075000 22.01670 0.43433 0.535670 0.47667 Example D 21.0167 22.158300 22.18330 0.24333 0.400000 0.38133 Example E 20.0667 20.283300 20.14170 0.29600 0.415330 0.39067 Example F 20.6583 21.066700 21.02500 0.34133 0.422000 0.43167 Example G 21.4500 22.008300 22.17500 0.30933 0.395000 0.34967 Example H 22.9417 23.891700 22.65830 0.33733 0.422000 0.34400 Example I 32.0333 33.266700 32.76670 0.28300 0.302330 0.26033 Example J 23.3833 23.758300 23.30000 0.34433 0.420670 0.33800 Example K 33.7250 33.708300 34.22500 0.30000 0.375330 0.29500

TABLE JJ Shear Hysteresis Shear Hysteresis (2HG05) Warp (2HG05) Filling 0 50 125 0 50 125 Parameter Washes Washes Washes Washes Washes Washes Example 1.2407 1.414670 1.21000 0.5727 0.600670 0.45330 A Example 1.2983 1.562330 1.30400 0.6270 0.724670 0.59230 B Example 1.4110 1.537670 1.34200 0.6723 0.715000 0.62330 C Example 3.7677 1.834670 1.61933 3.2570 1.103000 0.76230 D Example 1.3290 1.592670 1.48567 0.8907 0.869000 0.72970 E Example 1.8803 0.777670 0.80800 1.3053 0.485330 0.44800 F Example 2.8020 2.203000 2.17800 2.1960 1.340330 1.33870 G Example 1.2357 2.010330 2.24200 0.8807 1.396330 1.38970 H Example 2.2307 4.899670 5.02767 2.3563 4.347000 4.49430 I Example 1.5200 2.195670 2.43733 1.1197 1.395670 1.46300 J Example 3.2923 6.005000 7.25067 3.5930 5.752000 6.50470 K

TABLE KK Shear Hysteresis (2HG25) Shear Hysteresis (2HG25) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 1.9400 1.064700 1.79367 1.2880 2.055000 0.90630 Example B 2.2257 1.346300 1.91900 1.5510 2.280300 1.07870 Example C 2.2390 1.299000 1.98067 1.5400 2.252700 1.19470 Example D 7.8223 2.323300 2.60267 7.3877 3.065300 1.66030 Example E 5.0633 1.496000 2.09100 4.4080 2.290700 1.29530 Example F 5.3043 0.948700 1.27000 4.5470 1.275300 0.81500 Example G 6.6990 2.630000 3.39833 5.9423 3.522000 2.57800 Example H 1.8830 2.307000 2.98100 1.5247 2.819700 2.15000 Example I 5.9453 8.038700 8.10300 5.8533 8.313000 7.87800 Example J 2.3677 2.259700 3.24800 2.0150 3.041000 2.26470 Example K 7.2243 9.493700 10.82367 7.3383 9.329000 10.35630

TABLE LL Shear Hysteresis (2HG50) Shear Hysteresis (2HG50) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 3.089 3.456000 3.07830 2.560 2.344300 2.00830 Example B 3.641 3.792000 3.19170 3.029 2.831700 2.36200 Example C 3.614 3.845700 3.35530 3.029 2.810300 2.53730 Example D 11.349 5.678700 4.91330 10.753 5.091000 3.94800 Example E 10.141 3.730700 3.42100 9.827 3.054000 2.67300 Example F 11.387 2.752700 2.48570 10.804 2.388300 1.95400 Example G 10.268 5.884300 5.90670 9.731 5.192300 5.29000 Example H 3.021 4.163300 4.07170 2.538 3.850300 3.39070 Example I 10.130 10.638700 10.58770 9.561 10.374000 10.31430 Example J 3.483 4.272700 4.38070 3.275 3.603000 3.55800 Example K 12.040 11.258300 12.62270 11.815 11.752000 12.10130

TABLE MM Residual Shear Angle (RG05) Residual Shear Angle (RG05) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 1.59567 2.153700 2.05033 0.90133 1.227000 1.04467 Example B 1.35633 2.118000 2.12667 0.80100 1.243670 1.21200 Example C 1.52500 2.197000 2.05967 0.87800 1.255670 1.19533 Example D 1.08433 1.766000 1.87933 0.95733 1.099670 1.04733 Example E 0.54300 2.304000 2.34333 0.40700 1.421000 1.27533 Example F 0.86633 1.524700 1.62367 0.70667 1.033670 1.10933 Example G 0.85833 2.105000 2.03200 0.81133 1.274000 1.32533 Example H 1.64633 2.407300 2.68900 1.32633 1.686670 1.89500 Example I 0.81667 1.773700 1.95267 0.87533 1.567670 1.68700 Example J 1.69000 2.608700 2.80967 1.36700 1.812000 1.94000 Example K 1.10700 2.067700 2.21867 1.24100 1.857330 1.96800

TABLE NN Residual Shear Angle (RG25) Residual Shear Angle (RG25) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 2.49667 3.127330 3.03333 2.02633 2.173330 2.08567 Example B 2.32200 3.088330 3.13100 1.98033 2.309330 2.20200 Example C 2.41933 3.216330 3.03933 2.00633 2.279670 2.28933 Example D 2.25600 2.950670 3.01767 2.17667 2.316000 2.27667 Example E 2.07300 3.311670 3.30033 2.00333 2.437000 2.26967 Example F 2.37233 2.496330 2.55000 2.24533 2.019330 2.02133 Example G 2.28367 3.214000 3.17067 2.19267 2.501000 2.55067 Example H 2.49833 3.367670 3.57267 2.29667 2.784670 2.93067 Example I 2.17433 3.009000 3.14733 2.17433 2.898670 2.95833 Example J 2.62300 3.606670 3.74500 2.45600 2.932670 2.99867 Example K 2.41033 3.212000 3.31233 2.52000 3.066330 3.13333

TABLE OO Residual Shear Angle (RG50) Residual Shear Angle (RG50) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 3.9760 5.267000 5.21770 4.0303 4.785300 4.61900 Example B 3.7973 5.134700 5.21070 3.8673 4.859700 4.82470 Example C 3.9040 5.488000 5.14600 3.9453 4.934000 4.86870 Example D 3.2743 5.466300 5.69530 3.1717 5.089700 5.41270 Example E 4.1503 5.392300 5.40700 4.4680 4.978000 4.70430 Example F 5.1237 5.384700 4.99200 5.3377 5.084700 4.85630 Example G 3.5250 5.367300 5.51200 3.6003 4.946000 5.23730 Example H 4.0087 4.977000 4.87930 3.8227 4.648700 4.62200 Example I 3.7033 3.850300 4.11200 3.5537 3.740700 3.87700 Example J 3.8647 5.069000 5.05130 3.9990 4.672700 4.70970 Example K 4.0127 3.876300 3.86300 4.0720 3.797300 3.66170

TABLE PP Mean Deviation of Coefficient Mean Deviation of Coefficient of Friction (MMD) Warp of Friction (MMD) Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.021333 0.026667 0.02867 0.024000 0.020667 0.02367 Example B 0.024000 0.024000 0.02400 0.027667 0.023667 0.02500 Example C 0.024333 0.023667 0.02433 0.025000 0.023333 0.02300 Example D 0.039667 0.071667 0.07433 0.038667 0.032333 0.02733 Example E 0.024333 0.019333 0.02267 0.029000 0.027000 0.02600 Example F 0.035000 0.021667 0.02833 0.034667 0.032333 0.02767 Example G 0.056667 0.076667 0.09700 0.038000 0.031333 0.03100 Example H 0.014333 0.015333 0.01400 0.018333 0.021333 0.02067 Example I 0.016000 0.012000 0.01433 0.022000 0.018333 0.01767 Example J 0.016000 0.016333 0.01833 0.019333 0.022333 0.02500 Example K 0.012667 0.012333 0.01133 0.022333 0.018000 0.01767

TABLE QQ Surface Roughness (SMD) Surface Roughness (SMD) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 12.6457 12.194700 11.75230 6.2930 6.042700 5.76130 Example B 9.4970 9.081000 8.73870 5.8047 5.950000 6.37500 Example C 9.9760 9.096000 9.45800 5.3733 5.618300 6.00500 Example D 12.4050 11.195000 10.84230 7.4990 7.373300 6.21030 Example E 12.8140 12.872000 12.50500 7.1800 7.856000 7.74670 Example F 10.6303 10.471300 10.46900 7.6433 6.938700 7.01330 Example G 10.6733 10.235700 10.59570 7.1230 6.476000 6.66370 Example H 2.3677 2.738300 2.33400 4.4337 5.433000 4.86400 Example I 2.5200 1.987300 1.98030 5.3827 4.622000 4.18800 Example J 3.8980 2.532000 2.61830 5.0787 5.642000 4.88630 Example K 2.5487 2.035700 1.85130 6.0113 4.168700 4.01170

TABLE RR Linearity of Extension (LT) Linearity of Extension (LT) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 0.705 0.580670 0.58800 0.730 0.583000 0.62600 Example B 0.679 0.606330 0.61100 0.731 0.595330 0.63433 Example C 0.736 0.590670 0.62233 0.666 0.583670 0.64700 Example D 0.700 0.613330 0.61033 0.679 0.613670 0.65800 Example E 0.813 0.584000 0.64300 0.728 0.593330 0.70500 Example F 0.703 0.637670 0.63500 0.674 0.608330 0.62533 Example G 0.733 0.633670 0.66667 0.753 0.647000 0.61267 Example H 0.588 0.598670 0.60900 0.622 0.601670 0.60567 Example I 0.672 0.682000 0.70133 0.807 0.693000 0.71867 Example J 0.675 0.601670 0.64333 0.599 0.603000 0.61433 Example K 0.727 0.677000 0.69700 0.748 0.685330 0.75567

TABLE SS Tensile Resiliency (RT) Tensile Resiliency (RT) Warp Filling Parameter 0 Washes 50 Washes 125 Washes 0 Washes 50 Washes 125 Washes Example A 51.854 49.300700 48.44500 57.483 56.347700 55.96100 Example B 52.120 48.758000 48.70300 57.281 54.911300 54.25900 Example C 51.531 48.273300 47.83300 57.200 53.761700 53.68600 Example D 55.109 48.086000 49.20500 58.795 54.777000 55.18900 Example E 52.802 49.159700 47.17600 58.120 55.645300 56.80200 Example F 42.334 44.300700 46.11400 50.833 51.461000 51.80000 Example G 48.799 47.513000 47.20500 58.244 54.983000 54.36800 Example H 43.341 38.401700 39.45900 50.383 41.756300 37.85300 Example I 42.005 36.987300 33.71800 51.343 40.68700 39.71600 Example J 37.993 37.798300 36.32200 48.606 40.566300 37.97300 Example K 40.292 35.886700 32.63800 57.588 42.283300 39.91200

In addition, the hand improvements were achieved while the strength of the fabric was maintained, and in fact, some strength measurements were improved. In addition, the fabrics of the invention had superior ATPV, lower char length, better warp fray, superior drape and bending modulus, better wicking and soil release, and better combination of comfort characteristics with a particular level of FR.

Stated differently, the fabrics had comfort levels approximating those of cotton, while at durability levels approximating those of fabrics made from inherently FR fabrics. Furthermore, because of the improved soil release characteristics and reduced soil retention, it is expected that the fabrics would be less likely to hold onto oily stains that might otherwise adversely impact the FR potential of the fabrics.

In addition, the Handle-o-meter measurements on the unwashed fabrics of the present invention are substantially better than those of the conventional fabrics, which is indicative of the superior drape (and thus perceived comfort) that they possess.

The fabrics of the present invention have utility in a variety of end uses, including but not limited to protective apparel, industrial work apparel (i.e. that designed to be worn in an industrial environment and laundered under industrial wash conditions), military apparel, transportation vehicle interiors (including but not limited to aviation, boat, car, bus, train, RV etc. interiors), industrial fire barriers, home and office furnishings, office panels, and virtually anywhere that FR protection would be of advantage.

In the specification there has been set forth a preferred embodiment of the invention, and although specific terms are employed, they are used in a generic and descriptive sense only and not for purpose of limitation, the scope of the invention being defined in the claims. 

1. A woven flame resistant fabric comprising a plurality of multi-ply inherently flame resistant yarns, wherein at least a portion of the individual plies of said multi-ply inherently flame resistant yarns are separated from each other.
 2. A woven flame resistant fabric according to claim 1, wherein said inherently flame resistant yarns comprise fibers selected from the group consisting of meta-aramids, para-aramids, melamines, aramid fibers, fluoropolymers and copolymers thereof, chloropolymers, polybenzimidazole, polyimides, polyamideimides, partially oxidized polyacrylonitriles, novoloids, poly(p-phenylene benzobisoazoles), poly(p-phenylene benzothiazoles), polyphenylene sulfides, flame retardant viscose rayons, polyvinyl chloride homopolymers and copolymers thereof, polyetheretherketones, polyketones, polyetherimides, polylactides, melamine fibers, and combinations thereof.
 3. A woven flame resistant fabric according to claim 1, wherein said yarns define a plurality of fiber tangles comprised of fibers that are substantially intact and undamaged extending outwardly from at least one surface of the fabric.
 4. A woven flame resistant fabric according to claim 1, wherein said fabric is woven in a construction that is selected from the group consisting of plain weave, twill weave, basket weave, oxford weave, satin weave, and jacquard weave.
 5. A woven flame resistant fabric according to claim 1, wherein said woven fabric comprises warp yarns and filling yarns, and at least a plurality of said warp yarns are spun yarns.
 6. A woven flame resistant fabric according to claim 5, wherein said at least a plurality of said filling yarns are spun yarns.
 7. A woven flame resistant fabric according to claim 1, wherein said fabric comprises at least about 65% inherently flame resistant yarns.
 8. A woven flame resistant fabric according to claim 1, wherein said fabric consists essentially of inherently flame resistant yarns.
 9. A woven flame resistant fabric according to claim 1, wherein at least a portion of the individual plies that are separated from each other comprise individual fibers that are entangled with the fibers forming another individual ply.
 10. A flame resistant fabric comprising a plurality of spun yarns comprising inherently flame resistant fibers, wherein said fabric has first and second surfaces, and at least one of said surfaces comprises a plurality of fiber tangles comprised of fibers that are substantially intact and undamaged extending outwardly from said at least one surface of the fabric.
 11. A fabric according to claim 10, wherein at least a plurality of said spun yarns comprise a plurality of plies, and wherein said plies are at least partially separated from each other.
 12. A fabric comprising at least about 65% inherently flame resistant fibers wherein said fabric has a surface that has been chemically modified to achieve an ATPV rating of about 4 or greater.
 13. The fabric according to claim 12, wherein said fabric comprises at least about 90% inherently flame resistant fibers.
 14. The fabric according to claim 12, wherein said fabric has a soil release rating of about 2.5 or greater when soiled at 0 washes and tested after one wash, according to AATCC 130-1995 Test Method.
 15. The fabric according to claim 12, wherein said fabric has a soil release rating of about 3.0 or greater when soiled at 0 washes and tested after 1 wash, according to AATCC 130-1995 Test Method.
 16. The fabric according to claim 12, wherein said fabric has a Drop Disappearance of about 2 seconds or less.
 17. The fabric according to claim 12, wherein said fabric has been chemically modified through the application of about 0.25-5% owf of ethoxylated polyamide and about 0.25-5% owf of ethoxylated polyester.
 18. A woven flame resistant fabric comprising at least about 65% of inherently flame resistant fibers, wherein said fabric is defined by a plurality of interwoven warp and filling yarns, and a plurality of fibers forming said warp and filling yarns are entangled with each other to an extent sufficient to achieve a Warp Fray Value of about 10% or less when tested prior to washing.
 19. The fabric according to claim 18, wherein said fabric has a warp fray of less than about 5 when tested after 125 industrial launderings.
 20. The fabric according to claim 18, wherein said fabric comprises a plurality of fiber tangles comprised of fibers that are substantially intact and undamaged extending outwardly from a surface of said fabric.
 21. A fabric comprising at least about 65% inherently flame resistant fabrics, wherein said fabric has a Handle-o-meter reading of about 90 grams force or less in its as-produced form.
 22. The fabric according to claim 21, wherein said fabric comprises at least about 90% inherently flame resistant fibers.
 23. The fabric according to claim 21, wherein said fabric comprises a woven fabric having a weight of about 2 oz/sq yd to about 12 oz/sq yd.
 24. A woven fabric comprising at least about 65% inherently flame resistant fibers, wherein said fabric has a chemically modified surface and a bending modulus of about 0.6 or less when tested in a warp direction and in an as-produced form.
 25. The woven fabric according to claim 24, wherein said fabric comprises at least about 90% inherently flame resistant fibers.
 26. The woven fabric according to claim 24, wherein said fabric has a weight of about 2 to about 12 oz/sq yd.
 27. The woven fabric according to claim 24, wherein said fabric has been chemically modified through the application of an ethoxylated polyamide and an ethoxylated polyester.
 28. A woven fabric having a weight of about 4 to about 8 oz/sq yd, said fabric comprising at least about 90% inherently flame resistant fibers, wherein said fabric has a Drape Coefficient of about 60 or less.
 29. The woven fabric according to claim 28, wherein said fabric has a Drape Coefficient of about 40 or less.
 30. A woven fabric comprising at least about 65% inherently flame resistant fibers and a weight of about 4 to about 8 oz/sq yd, wherein said fabric has an ATPV rating of about 6 calories/cm² or greater.
 31. A woven fabric according to claim 30, wherein said fabric has been chemically treated to achieve a Vertical Wicking of about 5 inches or greater when tested in its as-produced form.
 32. A fabric comprising at least about 65% inherently flame resistant fibers and having a weight of about 4 to about 8 oz/sq yd, an ATPV of about 4 or greater and a DMIN of about 0.22 or less in its as-produced form.
 33. The fabric according to claim 32, wherein said fabric has a DMIN of about 0.21 or less in its as-produced form.
 34. The fabric according to claim 32, wherein said fabric comprises at least about 90% inherently flame resistant fibers.
 35. A fabric having a weight of about 4 to about 8 oz/sq yd and comprising at least about 90% of inherently flame resistant fibers, wherein said fabric has a WC of about 0.35 or greater.
 36. The fabric according to claim 35, wherein said fabric has a plurality of fiber tangles comprised of fibers that are substantially intact and undamaged extending outwardly from at least one surface of the fabric.
 37. A fabric comprising at least about 65% inherently flame resistant fibers, wherein said fabric has treatment of ethoxylated polyamide in an amount of about 0.25-5% owf and an ethoxylated polyester in an amount of about 0.25-5% owf.
 38. The fabric according to claim 37, wherein said fabric has a soil release rating of about 2.5 or greater when soiled at 0 washes and tested after one wash in accordance with AATCC 130-1995 (corn oil).
 39. The fabric according to claim 37, wherein said fabric is a woven fabric about 2 to about 12 oz/sq yd in weight, and said fabric has a soil release rating of about 3 or greater when soiled at 0 washes and tested after one wash in accordance with AATCC 130-1995 (corn oil.)
 40. A fabric comprising at least about 65% inherently flame resistant fibers and a chemical wicking treatment, wherein said fabric has a Drop Disappearance of about 2 seconds or less when tested in an unwashed condition.
 41. The fabric according to claim 40, wherein said fabric has a Drop Disappearance of about 1 second or less.
 42. The fabric according to claim 40, wherein said fabric has a Drop Disappearance of about 2 seconds or less after 50 washes
 43. The fabric according to claim 40, wherein said fabric has a Drop Disappearance of about 3 seconds or less after 125 washes.
 44. A fabric having a weight of about 2 to about 12 oz/sq yd and at least about 65% inherently flame resistant fibers, wherein a plurality of said fibers are entangled with each other, such that said fabric has an air permeability of about 70 cfm or greater when tested according to AATCC Test Method 737-1996, and an ATPV of about 6 or greater.
 45. A fabric having a weight of about 4 to about 8 oz/sq yd, said fabric comprising at least about 90% inherently FR fibers, wherein said fabric has a soil release rating of about 2.5 or greater for corn oil when tested according to AATCC Test Method 130-1995 in an unwashed condition, and a vertical wicking of about 5 inches or greater.
 46. A fabric according to claim 45, wherein said fabric has a soil release rating of about 3.5 or greater for corn oil when tested according to AATCC Test Method 130-95 when soilded at 48 washes and tested after 49 washes.
 47. A fabric according to claim 45, wherein said fabric comprises inherently flame resistant fibers selected from the group consisting of meta-aramids, para-aramids, melamines, aramid fibers, fluoropolymers and copolymers thereof, chloropolymers, polybenzimidazole, polyimides, polyamideimides, partially oxidized polyacrylonitriles, novoloids, poly(p-phenylene benzobisoazoles), poly(p-phenylene benzothiazoles), polyphenylene sulfides, flame retardant viscose rayons, polyvinyl chloride homopolymers and copolymers thereof, polyetheretherketones, polyketones, polyetherimides, polylactides, melamine fibers, and combinations thereof. 48-51. (canceled)
 52. A fabric made by the process of claim
 48. 53-54. (canceled) 